The question
This question that arose in a discussion with Ron Adin is quite simple:
For which pairs $k$ and $n$ does $n$ divide ${{n-2} \choose {k}}$?
Simple observations
It is easy to see that for every $k$ there are finitely many possible values of $n$. One way to see it is to note that if $n$ divides ${{n-2} \choose {k}}$ it also divides $(n-2)(n-3)\dotsb (n-k-1)$ and therefore also (if $n \ge k+2$) it must divide $(k+1)!$.
For $n=2k+2$, $\frac {1}{n} {{n-2} \choose {k}}=\frac {1}{2(k+1)}{{2k} \choose {k}}=\frac {1}{2}C_k$, where $C_k$ is the $k$-th Catalan number. So the question is when the $k$-th Catalan number is even. As $C_k={{2k+1} \choose {k}}-2 {{2k}\choose {k+1}}$, this is if and only if ${{2k+1} \choose {k}}$ is even and by Kummer's theorem this always happens, unless $k$ and $k+1$ have no common $1$ digits in base $2$, namely iff $k+1$ is a power of $2$. Maybe a similar analysis can be done in other cases as well, and perhaps a complete description is possible.
Experimenting
a little, it seems that given $n$ there are few values of $k$ such that $n \mid{{n-2} \choose {k}}$.
Motivation
These are the cases where vertex-regular $n$-vertex $k$-dimensional $\mathbb Q$-acyclic complexes with complete $(k-1)$-dimensional skeletons exist. We know (albeit by an indirect argument and not by an explicit construction) that whenever $d_1,d_2,\dotsc d_n$ are non-negative integers that sum up to ${{n-2} \choose {d}}$ then a $\mathbb Q$-acyclic complex with complete $(k-1)$-dimensional skeletons exists such that the degree of vertex $i$ (namely, the number of $k$-faces containing it) is $d_i + {{n-2} \choose {k-1}}$.
Related MO question: Seeking very regular $\mathbb Q$-acyclic complexes