Suppose that $A$ is a finite, nonempty set in an abelian group. If there is a group element with a unique representation as $a-b$ with $a,b\in A$, then none of $A-A$ and $2A$ are small: $$ \min\{|A-A|,|2A|\} \ge 2|A|-1; $$ this is almost immediate for the difference set, while the sumset case is a nontrivial result due to Kemperman and Scherk.
I need an analogue of this result for the additive energy of $A$ defined by $$ E(A):=\{(a_1,a_2,a_3,a_4)\in A^4\colon a_1+a_2=a_3+a_4\}. $$ A straightforward application of the Cauchy-Schwarz inequality gives the well-known estimate $E(A)\ge|A|^4/|2A|$. How small can $E(A)$ be given that there is an element with a unique representation as $a-b$ with $a,b\in A$? Given that there are "many" uniquely representable elements?
What I would need is an explicit estimate that works starting with very small values of $|A|$, not involving excessively large constants and the $O/o$-notation. Even an improvement by a lower-order term can be helpfull.